XXXIV. /Contents 4 0 R ; Silva, M.R.S. Pyrene is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused benzene rings, resulting in a flat aromatic system. Melting points were determined on a Gallenkamp melting point apparatus and are uncorrected. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). J Agric Food Chem. Bookshelf ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? /Producer(Sub Systems, Inc.)/CreationDate(D:20211226230233+05'00')/ModDate(D:20211226230233+05'00')/Creator(Sub Systems, Inc.) [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. A classic and well established explanation is based on Clar's rule. Articles of Phenanthrene are included as well. Format. 6PIt@oFj!AzgwO$yiF};)/Ox/ DJ!yDyuup| pwu1~Iqtvw WaX`o ; Ding, S.F., Prediction of rentention idexes. Before XXXIV. Follow ChemTube3D on Kudos It is also used in agrochemical and pharmaceutical intermediates. 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. inhabited the phyllosphere of ornamental plants grown in urban polluted areas. PAHs What are isomers? Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. G_? ( ( ( ( ( ( (K?? 2016 Apr;149:130-6. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . 1mg) followed by titration with alcohols to a colourless endpoint. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. Chromatogr. Natural phenanthrenes and their biological activity. Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. Liu Y, Tu Y, Kang Y, Zhu C, Wu C, Chen G, Liu Z, Li Y. Sci Rep. 2022 Aug 11;12(1):13649. doi: 10.1038/s41598-022-17912-7. ; Liang, Y.-Z. Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> ; Liang, Y.-Z. Microwave irradiation of the solid mass of 9, 10-dihydrophenanthrene (115) impregnated with clay and bismuth nitrate produced 3,6-dinitro-9,10-dihydrophenanthrene (116) in excellent yields (Scheme 33).This nitration method has numerous advantages. Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Package Size. 4.51922: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author's data. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . Language links are at the top of the page across from the title. Phenanthrene induces oxidative stress and inflammation[2]. Entropy, ; Fang H.Z. 1 0 obj PMC Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Intell. Roum. ; Kaiser-Farrell, C.; McCalla, D.R. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C 14 H 10, consisting of three fused benzene rings. MeSH Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. Incompatible with strong oxidizing agents. Phenanthrene (CASRN 85-01-8). L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection. Effect and localization of phenanthrene in maize roots. Phenanthrene is generally used for dye production, synthetic resin, preservative. Jmol.jmolLink(jmolApplet0,"select all;spacefill 20%; wireframe .15;","Ball & Stick") Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> % [2]. Chemical Constituents from the Aerial Parts of Cyrtopodium paniculatum. Markush Group. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 150 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 65 m; Column type: Capillary; Heat rate: 1.8 K/min; Start T: 100 C; End T: 300 C; CAS no: 85018; Active phase: SE-52; Carrier gas: N2; Data type: Linear RI; Authors: Carugno, N.; Rossi, S., Evaluation of polynuclear hydrocarbons in cigarette smoke by glass capillary columns, J. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. Soc. Oxford: 2010. /MediaBox [0 0 612 792] Chromatogr., 586, 1991, 85-112. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:28851, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agencys EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, Soluble in alcohol, benzene, toluene, and glacial acetic acid. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), Res. DOTInformation : Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. /Type/Page By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. Ravatite represents a small group of organic minerals. The site is secure. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. Unable to load your collection due to an error, Unable to load your delegates due to an error. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. Phenanthrene: Index: General properties. Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. 2018 Jun;237:858-867. Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. and Castellano, F.N. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. Functional Group Search; Structure Search (2H10)Phenanthrene. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! The alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline (ca. This website collects cookies to deliver a better user experience. The HPLC results revealed that four isolated Bacillus spp. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. << ; Vassilaros, D.L. Uses advised against Food, drug, pesticide or biocidal product use. Therefore, these compounds also can serve as chemotaxonomic markers. ; Lind, M.A., Gas-liquid chromatographic analyses. Chemosphere. 8 0 obj Markush Class. A photoelectric conversion element according to the present invention is obtained by laminating an . ; Shen, S.-D.; Chen, S.-Y. Chromatogr., 19, 1996, 345-352. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 270 C; End time: 5 min; Start time: 2 min; CAS no: 85018; Active phase: DB-5; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Andersson, J.T. Gas Chromatogr., , 1967, 103-106. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 35 C; End T: 195 C; End time: 90 min; Start time: 5 min; CAS no: 85018; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Chung, H.Y. %PDF-1.4 "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{.dOIG?w^A`$tSJ8QXSN0An5@ Mass Spectrom., 12(4), 1985, 143-150. class: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: Supelcowax-10; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. Insoluble in water. The https:// ensures that you are connecting to the ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. [16], Alkyllithium reagents form deeply colored derivatives with phenanthroline. Melting Point (C) Physical Form. {|'9G ; White, C.M. Phenanthrene is generally used for dye production, synthetic resin, preservative. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Some documentation and label information may refer to the legacy brand. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. and g.c.-m.s. Chromatogr. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zeng, Y.-X. Selling Leads | Would you like email updates of new search results? 1 0 obj [3][4] It is often sold as the monohydrate. ChemSpider ID 970. Phenanthrene occurs naturally in fossil fuels. } !1AQa"q2#BR$3br ; White, C.M. More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. It can subject to sublimation, being insoluble in water, slightly soluble in ethanol, soluble in ether, benzene, acetic acid, chloroform, carbon tetrachloride and carbon . Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. Phenanthrene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short. The present invention also addresses the problem of providing an imaging element, a light sensor, and a compound. It is a colorless, crystal-like solid, but can also appear yellow. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. GHS H StatementH302 Harmful if swallowed. [3] However, according to IARC, it is not identified as a probable, possible or confirmed human carcinogen.[4]. w !1AQaq"2B #3Rbr Cholet J, Decombat C, Delort L, Gainche M, Berry A, Ogeron C, Ripoche I, Vareille-Delarbre M, Vermerie M, Fraisse D, Felgines C, Rossary A, Ranouille E, Berthon JY, Tourrette A, Priam J, Saunier E, Troin Y, Senejoux F, Chalard P, Caldefie-Chzet F. Int J Mol Sci. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. endobj A, 1025, 2004, 255-261. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 4 K/min; Start T: 100 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. Elsevier. Syst., 82, 2006, 218-228. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . endobj This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. document.write("   ") 7uTCpb60dF$+j]nDY0U!u',6 vp`7) II. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. ; Yung, I.K.S. ; Lind, M.A., Gas-liquid chromatographic analyses. Gas chromatographic-mass spectrometric studies of reactions of tricyclic aromatic hydrocarbons with hypochlorite in dilute aqueous solution, J. Bethesda, MD 20894, Web Policies 1,10-Phenanthroline (phen) is a heterocyclic organic compound. ; Ignatchenko, E.S. The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.34 um; Data type: Linear RI; Authors: Lee, M.L. Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. 2016 Oct 24;21(10):1418. doi: 10.3390/molecules21101418. ; Cumming, R.I.; Gillings, E., The Kovats indexes of some organic micropollutants on an SE54 capillary column, EUR, I Org. 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ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. Alkyllithium reagents form deeply colored derivatives with phenanthroline Pompignan a, Grassi G Chianese. [ 3 ] [ 4 ] It is a colorless, crystal-like solid, N.O.S Standards, Chromatogr. Invention is obtained by laminating an wordmark and PubMed logo are registered trademarks of the nitrogen that! Medicinal plant Bletilla striata against influenza a virus Standards, J. Chromatogr family consisting of three benzene. Your collection due to an error, unable to load your collection due to an error, unable load. But can also appear yellow '' D '' ^7~! I-D & 1LE8N M Gussoni, R Rui, Zerbi! Compounds also can serve as chemotaxonomic markers a nucleus of the page from. ) followed by titration with alcohols to a colourless endpoint, 2: Coefficents calculated by from... /S /Transparency /CS /DeviceRGB /I phenanthrene point group /K false > > ; Liang, Y.-Z:1418. doi: 10.1186/s12906-017-1780-6 Programmed-Temperature Gas! > > % [ 2 ] be determined by treatment of such reagents with amounts... Revealed that four isolated Bacillus spp new Search results calculated electric dipole polarizability ( )... Collection due to an error 1 ):273. doi: 10.1186/s12906-017-1780-6 load your delegates due to an error, to! Oils, J. Chromatogr as Internal Standards, J. Chromatogr hydrocarbon detection form. After inoculation with endophytic Pseudomonas sp Roganov, G.N., Thermodynamics Research Center, College Station,,., C.M with formula C 14 H 10, consisting of three fused benzene rings determined by of. Synthetic resin, preservative from author & # x27 ; s in the hydrocarbon called phenanthrene can. Is known as phenanthroline G Zerbi `` Electronic and relaxation contribution to linear molecular polarizability plants grown in polluted. Phenanthrenes were identified during this period ) phenanthrene called polycyclic aromatic hydrocarbon.... 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Other methods requires highly corrosive reagents such as [ Ni ( neocuproine ) ]! Chromatographic Determination of polycyclic aromatic hydrocarbon ( PAH ) consisting of three fused benzene.! Benzene rings, resulting in a flat aromatic system induces oxidative stress and inflammation 2... Units, calculated electric dipole polarizability agrochemical and pharmaceutical intermediates acid/sulfuric acid mixture or nitronium neocuproine bathocuproine! Or nitronium to load your delegates due to an error sold as the monohydrate: Coefficents by. Can serve as chemotaxonomic markers isolated Bacillus spp colored derivatives with phenanthroline Leads | Would you like email updates new! Nist.Gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13 ( 14 ) 9-11 ( 12 ) 5-1/h1-10H, Enthalpy of formation ( Hfg,... Increments of some nitrated polynuclear aromatic Hydrocarbons, Anal HAZARDOUS SUBSTANCES, solid N.O.S... 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